ABIOTIC OR BIOTIC HYDROCARBONS
The concept of peak oil has been around for a very long time, a concept which simply means that we once we reached peak production i.e. “peak oil”, the total global production of petroleum will decline, never to reach the peak ever again. However this prediction hangs by a single, assumption: the hypothesis that petroleum might somehow originate from biological detritus in sediments near the surface of the Earth, the "biological hypothesis", if you like. The assumption is that these reserves are finite due to hydrocarbons being made up of fossilized organic matter that died, decayed and underwent chemical alterations hundreds of millions of years ago. It does seem that new discoveries are declining, and have been since the 1960s. Spare production capacity is practically gone. And the old, super-giant oil fields that the world depends upon for the majority of its production are nearing or past their all-time production peaks. In fact the largest oil field in the world, which is the Ghawar oil field in Saudi Arabia has already reached is peak and has declined in production since 2006 by some estimates1. The world's second largest oil field, the Burgan field in Kuwait, entered decline in November 2005. The IEA stated in November 2008 that an analysis of 800 oilfields showed the decline in oil production to be 6.7% a year, and that this would grow to 8.6% in 2030.
Fossil Fuels
The theory claims that oil is an organic 'fossil fuel' deposited in finite quantities near the planet's surface. These are formed by the anaerobic decomposition of organisms such as plankton hundreds of millions of years ago under conditions devoid of oxygen. These were later buried under increasing layers of mud and sediment thereby placing these biological detritus under immense pressure which over time caused it to undergo chemical changes which formed the low-carbon hydrocarbons such as methane (CH4 ), liquid petroleum and high carbon hydrocarbons such as coal. So the theory goes.
Abiotic or Abiogenic or Inorganic Fuels
During the latter half of the 20th century, with advances in geophysics and geochemistry, the vast majority of scientists lined up on the side of the biotic theory. However a small group of mostly Russian scientists such as Professor Nikolai Kudryavtsev, and a tiny handful of Western scientists, among them the late Cornell University physicist Thomas Gold have held out for an abiotic (also called abiogenic or inorganic) theory. Gold's book The Deep Hot Biosphere (1998) stirred considerable controversy among the public on the questions of where oil comes from and how much of it there is. Gold argued that hydrocarbons existed at the time of the solar system's formation, and are known to be abundant on other planets (Jupiter, Saturn, Uranus, and some of their moons) where no life is presumed to have flourished in the past and hence does not “rely” on biotic origins.
The modern Russian -Ukrainian theory2 of deep, abiotic petroleum origins proposes that petroleum is a primordial material of deep origin which over time erupts into the Earth’s crust. Bluntly speaking, according to the abiotic theories, petroleum is not a “fossil fuel” and has no intrinsic connection with dead dinosaurs or any other biological origins “in the sediments” or anywhere else. To the proponents of this theory, the discovery of the eleven major oil and gas fields in the Dnieper-Donets2 Basin by drilling at the depths of the crystalline basement as opposed to discovery at the sedimentary layers, is proof of the abiotic oil theory. Fifty commercial oil and gas fields have also been developed in a 100 × 600 km strip of the northern flank of the Dneiper-Donets Basin. However, it should be emphasized that 15 of the fields in the Dneiper-Donets Basin exploit both Carboniferous sediments and lower crystalline basement rocks but only 2 exploit the crystalline basement exclusively2,6. Further “support” of the abiotic theory it seems, can be seen by the fact that more than 80 oil and gas fields in the Caspian district have been explored and developed in crystalline basement rock as opposed to drilling at the sedimentary rocks layers of which lends further support to the abiotic theory. Exploration in the western Siberian cratonic rift sedimentary basin has led to the development of 90 petroleum fields of which 80 produce either partly or entirely from the crystalline basement.
Support for Abiotic Formation of Petroleum
In 2007 the Cassini-Huygens3,4 probe determined the chemical composition of a dark coloured liquid in a lake on Titan (one of Saturn’s moons) by the way it reflected light (a technique known as spectrometry). More than 99.9 % of the light that entered the lake never got out again. The scientists determined that the specific absorption of light is exactly 2-micron wavelengths a tell-tale signature of ethane. Ethane is “synthesized” by a chemical reaction between the solar radiation and atmospheric methane. And since the surface temperature of Titan is -300oF (-184oC) Ethane can easily exist in liquid form. But where does the methane come from? Titan does not have any life or rather did not have any carbon-based life to form fossilized based methane. It seems that hydrocarbons in the case of Titan can form independent of biological matter.
Fig 1 – Schematic Showing Liquid Ethane Formation on Titan
Does this lend at least some support to the fact that hydrocarbons can form without the presence of any biological matter?
Further, recently, for the first time, scientists have found that ethane and heavier hydrocarbons can be synthesized under the pressure-temperature conditions of the upper mantle, the layer of Earth under the crust and on top of the core. The research was conducted by scientists at the Carnegie Institution's Geophysical Laboratory, with colleagues from Russia and Sweden, and is published in the July 26 2009, advanced on-line issue of Nature Geoscience.
Methane (CH4) is the main constituent of natural gas, while ethane (C2H6) is used as a petrochemical feedstock. Both of these hydrocarbons, and others associated with fuel, are called saturated hydrocarbons because they have simple, single bonds and are saturated with hydrogen. Using a diamond anvil cell and a laser heat source, the scientists first subjected methane to pressures exceeding 20 thousand times the atmospheric pressure at sea level and temperatures ranging from 1,300 F° to over 2,240 F°. These conditions mimic those found 40 to 95 miles deep inside the Earth. The methane reacted and formed ethane, propane, butane, molecular hydrogen, and graphite. The scientists then subjected ethane to the same conditions and it produced methane. This transformation suggest heavier hydrocarbons could exist deep down the earth’s crust.
Fig 2- Schematics of the core of a diamond anvil cell Fig3-What it really looks like.
The diamond size is a few millimeters at most
If Abiotic Fuels Exists At Depths of Igneous or Metamorphic Rocks or at Greater Depths, Would it be Viable?
A new study by the US Department of Energy and Lawrence Livermore Lab5 suggests that there may be huge methane deposits in Earth's mantle, 60 to 120 miles deep. But today oil companies are capable of drilling only as deep as six miles, in sedimentary rock. Any attempt to drill into igneous and metamorphic rock (crystalline rock), would limit the current capability to only two miles, because to drill to a depth remotely approaching the mantle, would cause the steel drill tubes to be either thoroughly crushed, or melted by the pressures and temperatures at that depth.
For liquid hydrocarbons such as oil to exist at great depths, it would have to remain liquid at depths and pressures below about 15,000 feet and above 275 degrees F. At these depths and pressures, the hydrocarbon bonds tend to break down. What remains after these molecular bonds are severed is methane, whose molecule contains only a single carbon atom. For petroleum geologists this is not just a matter of theory, but of repeated and sometimes costly experience. They typically encounter an oil "window" that exists from roughly 7,500 feet to 15,000 feet, within which temperatures are appropriate for oil formation. Any depths outside (deeper) of this range will most likely come up with a dry hole or, at best, natural gas only.
That is why the conventional theory of petroleum formation connects oil with the process of sedimentation. And, indeed, nearly all of the oil that has been discovered over the past century and a half is associated with sedimentary rocks. On the other hand, it isn’t difficult to find rocks that once existed at great depths where, according the theories of the Russians, conditions should have been perfect for abiotic oil formation or the accumulation of primordial petroleum, but such rocks typically contain no traces of hydrocarbons. In the very rare instances where small amounts of hydrocarbons are seen in igneous or metamorphic rocks, the latter are invariably found near hydrocarbon-bearing sedimentary rocks, and the hydrocarbons in both types of rock contain identical biomarkers. The simplest explanation it seems would be that, in those cases is that the hydrocarbons migrated from the sedimentary rocks to the igneous-metamorphic rocks.
Support for Biotic Formation of Petroleum
Geologists trace the source of the carbon in hydrocarbons through analysis of its isotopic balance. Natural carbon is nearly all isotope 12 (C-12), with 1.11 percent being isotope 137(C-13). Organic material, however, usually contains less C-13, because photosynthesis in plants preferentially selects C-12 over C-138. Oil and natural gas typically show a C-12 to C-13 ratio similar to that of the biological materials from which they are assumed to have originated. The C-12 to C-13 ratio is also a generally observed property of petroleum and it seems lends support to the biotic theory and it is not merely an occasional aberration.
In addition, oil typically contains biomarkers - porphyrins, isoprenoids, pristane, phytane, cholestane, terpines, and clorins - which are related to biochemicals such as chlorophyll and hemoglobin9. The chemical fingerprint of oil assumed to have been formed from, for example, algae is different from that of oil formed from plankton. Thus geochemists can (and routinely do) use biomarkers to trace oil samples to specific source rocks.
Abiotic theorists hypothesize that oil picks up its chemical biomarkers through contamination from bacteria living deep in the Earth's crust (Gold's "deep, hot biosphere") or from other buried bio-remnants. However, the observed correspondences between biomarkers and source materials are not haphazard, but instead systematic and predictable on the basis of the biotic theory. For example, biomarkers in source rock can be linked with the depositional environment; that is, source rocks with biomarkers characteristic of land plants are found only in terrestrial and shallow marine sediments, while petroleum biomarkers associated with marine organisms are found only in marine sediments.
Conclusion
There is no way to conclusively prove that no petroleum is of abiotic origin. Science is an ongoing search for truth, and theories are continually being altered or scrapped as new evidence appears. However, the assertion that all oil is abiotic requires extraordinary support, because it must overcome abundant evidence, already cited, to tie specific oil accumulations to specific biological origins through a chain of well-understood processes that have been demonstrated, in principle, under laboratory conditions. The proponents of the abiotic theories it seems insinuate that petroleum may be in unlimited supply if it’s origins are connected to non-biotic origins. However is this good? It seems that if humans accept the theory of peak oil and the inevitable depletion of petroleum to a level where we are compelled to find and use other energy sources which hopefully will not have such a deleterious effect to our climate and environment, then there is after all a silver lining to the biotic theory.
Notes: This article is simply the author’s opinion and interpretation of the various theories on the origins of Hydrocarbons and in no way represents the author’s “original work” . This topic is of interest to the author not least of which petroleum governs so much of our modern lives, and is vital to maintaining our day-today living standard. However, petroleum as a primary energy source, is also the cause of so much instability in the world today and in the recent past, due to the geopolitical manoeuvring by some countries who will stop at nothing to obtain energy-security, and is also it seems, the cause of adverse affects to our climate and environment.1. http://www.theoildrum.com/node/2325
2. http://www.gasresources.net/DDBflds2.htm
3. http://www.wired.com/wiredscience/2008/07/lake-of-petrole/
4. http://saturn.jpl.nasa.gov/multimedia/products/pdfs/20060926_CHARM_Waite.pdf
5. http://www.eurekalert.org/pub_releases/2004-09/dlnl-mid091304.php
6. Krayushkin, V. A., Tchebanenko, T. I., Klochko, V. P.,Dvoyanin, Ye. S. and Kenney, J. P. (2001) The exploration and development of twelve major and one giant oil and gas fields on the northern flank of the Dnieper-Donets Basin. Energia, 22/3, 44–47.\
7. Surface operations in petroleum production, Volume 2 By George V. Chilingar, John O. Robertson, Sanjay Kumar
8. http://www.madsci.org/posts/archives/2003-06/1055532737.Bc.r.html
9. http://www.oiltracers.com/biomarker.html